DERANGEMENT IN NICOTINAMIDE ADENINE DINUCLEOTIDE (NAD+) METABOLISM IS OBSERVED DURING ACUTE KIDNEY INJURY AMONG MALE AGRICULTURAL WORKERS AT RISK FOR MESOAMERICAN NEPHROPATHY

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DERANGEMENT IN NICOTINAMIDE ADENINE DINUCLEOTIDE (NAD+) METABOLISM IS OBSERVED DURING ACUTE KIDNEY INJURY AMONG MALE AGRICULTURAL WORKERS AT RISK FOR MESOAMERICAN NEPHROPATHY
Nathan
Raines
Dominic Leone nleone@bu.edu Boston University School of Public Health Epidemiology Boston
Juan Jose Amador juanjoseamador3011@gmail.com Boston University School of Public Health Epidemiology Boston
Damaris Lopez-Pilarte dalp1342@gmail.com Boston University School of Public Health Epidemiology Boston
Oriana Ramirez oriana.ramirez@isglobal.org Barcelona Institute for Global Health ISGlobal Barcelona
Iris Delgado idelgado@bu.edu Boston University School of Public Health Epidemiology Boston
Lauren Francey lfrancey@bidmc.harvard.edu Beth Israel Deaconess Medical Center Medicine / Nephrology Boston
Jessica Leibler jleibler@bu.edu Boston University School of Public Health Environmental Health Boston
John Asara jasara@bidmc.harvard.edu Beth Israel Deaconess Medical Center Signal Transduction Boston
Madeleine Scammell mls@bu.edu Boston University School of Public Health Epidemiology Boston
Samir Parikh Samir.Parikh@UTSouthwestern.edu University of Texas Southwestern Medical School Medicine / Nephrology Dallas
Daniel Brooks danbrook@bu.edu Boston University School of Public Health Epidemiology Boston
David Friedman dfriedma@bidmc.harvard.edu Beth Israel Deaconess Medical Center Medicine / Nephrology Boston
 
 
 

Mesoamerican Nephropathy (MeN) is a chronic kidney disease (CKD) in Central America which may be caused by heat stress leading to recurrent episodes of acute kidney injury (AKI). Biopsy features of MeN are not sufficiently specific to identify a causal injury mechanism, but broadly demonstrate tubular injury with ischemic features and mononuclear cellular inflammation. AKI caused by ischemia and inflammation is characterized by deranged biosynthesis of nicotinamide adenine dinucleotide (NAD+), which can be assayed in vivo as a rise in the urinary quinolinate to tryptophan (Q/T) ratio. NAD+ biosynthetic derangement in AKI is of particular interest because it may be mitigated by administration of nutritional precursors such as nicotinamide to protect against injury.


Using a paired case-control design, we investigated differences in urinary Q/T and other NAD+ related metabolites in a male sugarcane worker population with high rates of MeN in Nicaragua. Hypotheses are presented in Table 1




Among 327 sugarcane workers studied, we identified 45 individuals with serum creatinine (sCr) >1.3mg/dL present for <6 months as our “AKI” group, and matched them 1:1 based on age and job category with two comparison groups. Our primary comparison group, “no kidney injury,” had sCr <1.1mg/dL. Our secondary comparison group, “CKD,” had sCr >1.3mg/dL for >6 months, and were additionally matched 1:1 for sCr. We measured urine metabolites using liquid chromatography - coupled tandem mass spectrometry. Statistical comparisons were made using the Wilcoxon Signed Rank Test. 


Urine Q/T was significantly higher in workers with AKI than in those with no kidney injury (median [IQR] 0.104 [0.074 to 0.167] vs 0.060 [0.045 to 0.091], p < 0.0001) and marginally higher than in workers with CKD (0.086 (0.063 to 0.142), p = 0.059; Figure 1). Urine levels of other NAD+-related metabolites, most notably the NAD+ precursor nicotinamide and its breakdown product methylnicotinamide, also differed between AKI and comparison groups (Figure 2).

Workers at risk for MeN who develop AKI demonstrate elevated urine Q/T ratio compared to those with no kidney injury, consistent with NAD+ biosynthetic derangement and ischemic / inflammatory kidney injury. Lower urinary levels of nicotinamide, the main circulating NAD+ precursor in the body, along with its breakdown product methylnicotinamide suggest increased NAD+ demand in workers with AKI. Our finding that the directionality of differences in key metabolites between the AKI and NoKI groups persists between the AKI and CKD groups is evidence that these metabolites likely reflect metabolic features of AKI, and not just differences in clearance of these metabolites driven by decreased kidney function. Limitations include the cross-sectional nature of this study and limited generalizability beyond male sugarcane workers in Nicaragua. NAD+ biosynthetic derangement, as evidenced by increased urine Q/T ratio and alterations in other NAD+ precursor metabolites, is present during AKI among male sugarcane workers at risk for MeN. Therapeutic targeting with nicotinamide supplementation to boost NAD+ biosynthesis should be investigated to prevent AKI in this setting.

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